Theory of piezoelectricity, electrostriction, and pyroelectricity in molecular crystals.

Pyroelectricity of Molecular Crystals: Benzene Derivatives

für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...

Piezoelectric Negative Capacitance

A thermodynamic model was constructed to analyze the negative capacitance effect in the presence of piezoelectricity. The model demonstrated that while piezoelectricity can lead to negative capacitance in principle, it is not strong enough in practice due to the unphysical amounts of charge and strain required. The inclusion of higher-order electromechanical coupling such as electrostriction ca...

Bulk characterization methods for non-centrosymmetric materials: second-harmonic generation, piezoelectricity, pyroelectricity, and ferroelectricity.

Characterization methods for bulk non-centrosymmetric compounds are described. These methods include second-harmonic generation, piezoelectricity, pyroelectricity, and ferroelectricity. In this tutorial review with each phenomenon, details are given of the measurement techniques along with a brief history and background. Finally, data interpretation is discussed.

Origin and structure of polar domains in doped molecular crystals

Doping is a primary tool for the modification of the properties of materials. Occlusion of guest molecules in crystals generally reduces their symmetry by the creation of polar domains, which engender polarization and pyroelectricity in the doped crystals. Here we describe a molecular-level determination of the structure of such polar domains, as created by low dopant concentrations (<0.5%). Th...

On the entanglement of electrostriction and non-linear piezoelectricity in non-centrosymmetric materials